Thermodynamics Relations - Proof 5

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For the Vander Waals gas

From Equn.3.4,

   → (5.1)

For the Vander Waals gas,

i.e.,

   → (5.2)

differentiating with respect to T at constant V,

   → (5.3)

Substituting from Equn.5.3 in Equn.5.1,

   → (5.4)
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Last Modified on: 04-Feb-2022

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