→ I
→ II
→ III
→ IV
Fundamental thermodynamic property relations for a fluid of constant
composition are as follows:
→ I → II
→ III
→ IV
Criterion of exactness for a differential expression:
If
, then the total differnential of F
is
defined as
→ V
Otherwise,
where,
and
By further differentiation, we obtain
and
Since the order of differentiation in mixed second derivatives is
immaterial, these equations give
Equation VI serves as a criterion of exactness, when F is a
function of x & y
→ VI
Last Modified on: 01-May-2024
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